PERTANIKA JOURNAL OF SCIENCE AND TECHNOLOGY

 

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ISSN 0128-7680

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The Influence of MAPP and MAPE Compatibilizers on Physical and Mechanical Properties of 3D Printing Filament Made of Wood Fiber/Recycled Polypropylene

Nuzaimah Mustafa, Yusliza Yusuf, Syahibudil Ikhwan Abdul Kudus, Nadlene Razali, Dwi Hadi Sulistyarini, Mohd Hafizi Halim and Aenderson Chaong Anak Ujih

Pertanika Journal of Science & Technology, Volume 32, Issue S2, December 2024

DOI: https://doi.org/10.47836/pjst.32.S2.06

Keywords: 3D printing, compatibilizer, filament, wood fiber, recycled polypropylene, MAPP, MAPE, mechanical properties

Published on: 14 June 2024

This study aims to develop 3D printing filament composites that support sustainability and waste reduction goals by utilizing wood waste and recycled polypropylene. This study evaluated the effect of Maleic Anhydride Polyethylene (MAPE) and Maleic Anhydride Polypropylene (MAPP) compatibilizers on the mechanical properties of the filament. The study found that r-WoPPc filament with MAPP and MAPE had higher tensile strength compared to r-WoPPc with significant increments of 13% and 74%, respectively, compared to v-WoPPc. The flexural strength of r-WoPPc increased by 18% and 60% after adding optimum loading MAPP and MAPE, respectively. The finding also reveals a significant enhancement in the tensile and flexural strength of the composite, proportional to the increase in MAPP percentage. In contrast, as the MAPE content increases, the tensile strength and flexural strength of the r-WoPPc experience a gradual decrease. Consequently, the addition of MAPP and MAPE improved the interfacial adhesion between wood and polypropylene, as revealed by the surface morphology of the r-WoPPc tensile fractured surface. Moreover, the reduced water absorption in r-WoPPc is attributed to the enhanced interfacial adhesion between wood fibers and the r-PP matrix, associated with improved tensile and flexural strength. The highest tensile strength of r-WoPPc with MAPP absorbs 14% water, while the lowest tensile strength absorbs 26%. Likewise, the highest tensile strength of r-WoPPc with MAPE absorbs only 0.8% water, compared to the lowest strength, which absorbs 2% water. This study demonstrated the potential for producing 3D printing filament from recycled polypropylene and wood waste, which benefits sustainability.

  • Aida, H. J., Nadlene, R., Mastura, M. T., Yusriah, L., Sivakumar, D., & Ilyas, R. A. (2021). Natural fibre filament for fused deposition modelling (FDM): A review. International Journal of Sustainable Engineering, 14(6), 1988–2008. https://doi.org/10.1080/19397038.2021.1962426

  • Amir, N., Abidin, K. A. Z., & Shiri, F. B. M. (2017). Effects of fibre configuration on mechanical properties of banana fibre/PP/MAPP Natural fibre reinforced polymer composite. Procedia Engineering, 184, 573–580. https://doi.org/10.1016/j.proeng.2017.04.140

  • ASTM [American Society for Testing and Materials]. (2017). ASTM D570-98 Standard test method for water absorption of plastics. ASTM International.

  • ASTM [American Society for Testing and Materials]. (2022). ASTM D638 Standard test method for tensile properties of plastics. ASTM International.

  • ASTM [American Society for Testing and Materials]. (2017). ASTM D790 Standard test methods for flexural properties of unreinforced and reinforced plastics and electrical insulating materials. ASTM International.

  • Atiqah, A., Jawaid, M., Ishak, M. R., & Sapuan, S. M. (2018). Effect of alkali and silane treatments on mechanical and interfacial bonding strength of sugar palm fibers with thermoplastic polyurethane. Journal of Natural Fibers, 15(2), 251–261. https://doi.org/10.1080/15440478.2017.1325427

  • Baykus, O., Mutlu, A., & Dogan, M. (2016). The effect of pre-impregnation with maleated coupling agents on mechanical and water absorption properties of jute fabric reinforced polypropylene and polyethylene biocomposites. Journal of Composite Materials, 50(2), 257–267. https://doi.org/10.1177/0021998315573

  • Billah, M. M., Rabbi, M. S., & Hasan, A. (2022). Injection molded discontinuous and continuous rattan fiber reinforced polypropylene composite: Development, experimental and analytical investigations. Results in Materials, 13, Article 100261. https://doi.org/10.1016/j.rinma.2022.100261

  • Bütün, F. Y., Sauerbier, P., Militz, H., & Mai, C. (2019). The effect of fibreboard (MDF) disintegration technique on wood polymer composites (WPC) produced with recovered wood particles. Composites Part A: Applied Science and Manufacturing, 118, 312–316. https://doi.org/10.1016/j.compositesa.2019.01.006

  • Çavuş, V. (2020). 1 Selected-properties of mahogany wood flour filled polypropylene composites: The effect of maleic anhydride-grafted polypropylene (MAPP). BioResources, 15(2), 2227–2236. https://doi.org/10.15376/biores.15.2.2227-2236

  • Dhanalakshmi, S., Ramadevi, P., & Basavaraju, B. (2017). A study of the effect of chemical treatments on areca fiber reinforced polypropylene composite properties. Science and Engineering of Composite Materials, 24(4), 501–520. https://doi.org/10.1515/secm-2015-0292

  • Hao, X., Xu, J., Zhou, H., Tang, W., Li, W., Wang, Q., & Ou, R. (2021). Interfacial adhesion mechanisms of ultra-highly filled wood fiber/polyethylene composites using maleic anhydride grafted polyethylene as a compatibilizer. Materials and Design, 212, Article 110182. https://doi.org/10.1016/j.matdes.2021.110182

  • Keener, T. J., Stuart, R. K., & Brown, T. K. (2004). Maleated coupling agents for natural fibre composites. Composites Part A: Applied Science and Manufacturing, 35(3), 357–362. https://doi.org/10.1016/j.compositesa.2003.09.014

  • Khalid, M. Y., Imran, R., Arif, Z. U., Akram, N., Arshad, H., Rashid, A. A., & Márquez, F. P. G. (2021). Developments in chemical treatments, manufacturing techniques and potential applications of natural-fibers-based biodegradable composites. Coatings, 11(3), Article 293. https://doi.org/10.3390/coatings11030293

  • Kristiawan, R. B., Imaduddin, F., Ariawan, D., Ubaidillah, & Arifin, Z. (2021). A review on the fused deposition modeling (FDM) 3D printing: Filament processing, materials, and printing parameters. Open Engineering, 11(1), 639–649. https://doi.org/10.1515/eng-2021-0063

  • Mu, B., Wang, H., Hao, X., & Wang, Q. (2018). Morphology, mechanical properties and dimensional stability of biomass particles/high density polyethylene composites: Effect of species and composition. Polymers, 10(3), Article 308. https://doi.org/10.3390/polym10030308

  • Ou, R., Xie, Y., Wolcott, M. P., Sui, S., & Wang, Q. (2014). Morphology, mechanical properties, and dimensional stability of wood particle/high density polyethylene composites: Effect of removal of wood cell wall composition. Materials and Design, 58, 339–345. https://doi.org/10.1016/j.matdes.2014.02.018

  • Petchwattana, N., Channuan, W., Naknaen, P., & Narupai, B. (2019). 3D printing filaments prepared from modified poly(lactic acid)/teak wood flour composites: An investigation on the particle size effects and silane coupling agent compatibilisation. Journal of Physical Science, 30(2), 169–188. https://doi.org/10.21315/jps2019.30.2.10

  • Razak, Z., Sulong, A. B., Muhamad, N., Haron, C. H. C., Mohd Khairol, M. K. F., Tholibon, D., Tharazi, I., & Ismail, N. F. (2018). The effects of maleic anhydride grafted PP (MAPP) on the mechanical properties of injection moulded kenaf/CNTs/PP composites. Sains Malaysiana, 47(6), 1285–1291. https://doi.org/10.17576/jsm-2018-4706-25

  • Silva, N. F. I., Filho, J. E. S., Santos, T. G. C., Chagas, J. D. S., Medeiros, S. A. S. L. D., Santos, E. B. C., Wellen, R. M. R., Silva, L. B. D., Carvalho, L., Nunes, M. A. B. S., & Santos, A. S. F. E. (2021). Biocomposites based on poly(hydroxybutyrate) and the mesocarp of babassu coconut (Orbignya phalerata Mart.): Effect of wax removal and maleic anhydride-modified polyethylene addition. Journal of Materials Research and Technology, 15, 3161–3170. https://doi.org/10.1016/j.jmrt.2021.09.008

  • Sosiati, H., Nahyudin, A., Wijayanti, D. A., Triyana, K., & Sudarisman. (2018). Effect of alkali treatment and MAPP addition on tensile strength of sisal/polypropylene composites. Journal of Advanced Manufacturing Technology, 12(2), 65–78.

  • Yuan, Q., Wu, D., Gotama, J., & Bateman, S. (2008). Wood fiber reinforced polyethylene and polypropylene composites with high modulus and impact strength. Journal of Thermoplastic Composite Materials, 21(3), 195–208. https://doi.org/10.1177/0892705708089472

  • Zhang, J., Li, Y., Xing, D., Wang, Q., Wang, H., & Koubaa, A. (2019). Reinforcement of continuous fibers for extruded wood-flour/HDPE composites: Effects of fiber type and amount. Construction and Building Materials, 228, Article 116718. https://doi.org/10.1016/j.conbuildmat.2019.116718

  • Zhou, H., Li, W., Hao, X., Zong, G., Yi, X., Xu, J., Ou, R., & Wang, Q. (2022). Recycling end-of-life WPC products into ultra-high-filled, high-performance wood fiber/polyethylene composites: A sustainable strategy for clean and cyclic processing in the WPC industry. Journal of Materials Research and Technology, 18, 1–14. https://doi.org/10.1016/j.jmrt.2022.02.091

ISSN 0128-7680

e-ISSN 2231-8526

Article ID

JST(S)-0641-2024

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