PERTANIKA JOURNAL OF SCIENCE AND TECHNOLOGY

 

e-ISSN 2231-8526
ISSN 0128-7680

Home / Regular Issue / JST Vol. 33 (S3) 2025 / JST(S)-0653-2024

 

Enhancing Leachate Treatment with Electrocoagulation: A Computational Approach Using Response Surface Methodology

Mahmoud A. M. Al-Alwani, Alia Atasha Arisucman, Zadariana Jamil and Azianabiha A Halip Khalid

Pertanika Journal of Science & Technology, Volume 33, Issue S3, December 2025

DOI: https://doi.org/10.47836/pjst.33.S3.08

Keywords: Current intensity, electrocoagulation process, electrode distance, leachate treatment, process optimisation, Response Surface Methodology (RSM)

Published on: 2025-04-24

Malaysia's growing population and industrialisation have increased solid waste accumulation in landfills, leading to a rise in leachate production. Leachate, a highly contaminated liquid from landfills, poses environmental risks and affects water quality. Conventional leachate treatments are costly and time-consuming due to the need for additional chemicals. Therefore, the Electrocoagulation process could be used as an alternative method. Electrocoagulation is an electrochemical method of treating water by eliminating impurities by applying an electric current. In the present study, the optimisation of contaminant removal was investigated using Response Surface Methodology. Three parameters were considered for optimisation: the current, concentration of leachate, and the electrodes’ distance. The outcome of this study includes ANOVA analysis, mathematical modelling and 3D surface plot modelling. The optimum condition for contaminants removal was obtained at a current of 4 Amp, a concentration of leachate of 90.95%, and an electrode distance of 3 cm. The outcomes obtained under these conditions were about 47.85% and 76.32% removal of COD and turbidity, respectively. Both percentage COD and turbidity removal models achieved significant results, demonstrating that at least one of the independent variables has a significant impact on the dependent variable.

  • Ameli, F., Hashemi, H., Samaei, M. R., Asgari, E., & Mohammadian Fazli, M. (2024). Enhanced reducing leachate pollution index through electrocoagulation using response surface methodology. Heliyon, 10(18), e38134. https://doi.org/10.1016/j.heliyon.2024.e38134

    Apaydin, Ö., & Özkan, E. (2020). Landfill leachate treatment with electrocoagulation: Optimization by using Taguchi method. Desalination and Water Treatment, 173, 65-76. https://doi.org/10.5004/DWT.2020.24719

    Bandala, E. R., Liu, A., Wijesiri, B., Zeidman, A. B., & Goonetilleke, A. (2021). Emerging materials and technologies for landfill leachate treatment: A critical review. Environmental Pollution, 291, 118133. https://doi.org/10.1016/J.ENVPOL.2021.118133

    Das, P. P., Sharma, M., & Purkait, M. K. (2022). Recent progress on electrocoagulation process for wastewater treatment: A review. Separation and Purification Technology, 292, 121058. https://doi.org/10.1016/J.SEPPUR.2022.121058

    Detho, A., Kadir, A. A., & Azhar, M. A. (2024). Comparative analysis of contaminant levels in leachate and soil from young and old landfills. Pertanika Journal of Science and Technology, 32(5), 2299-2312. https://doi.org/10.47836/pjst.32.5.20

    Ding, J., Jiang, M., Zhao, G., Wei, L., Wang, S., & Zhao, Q. (2021). Treatment of leachate concentrate by electrocoagulation coupled with electro-Fenton-like process: Efficacy and mechanism. Separation and Purification Technology, 255, 117688. https://doi.org/10.1016/j.seppur.2020.117668

    Faheem, K., Khan, S. U., Washeem, M., & Khan, S. U. (2022). Energy efficient removal of COD from landfill leachate wastewater using electrocoagulation: Parametric optimization using RSM. International Journal of Environmental Science and Technology, 19(5), 3625-3636. https://doi.org/10.1007/s13762-021-03277-3

    Galvão, N., de Souza, J. B., & de Sousa Vidal, C. M. (2020). Landfill leachate treatment by electrocoagulation: Effects of current density and electrolysis time. Journal of Environmental Chemical Engineering, 8(5), 104368. https://doi.org/10.1016/j.jece.2020.104368

    Gasmi, A., Elboughdiri, N., Ghernaout, D., Hannachi, A., Halim, K. S. A., & Khan, M. I. (2022). Electrocoagulation process for removing dyes and chemical oxygen demand from wastewater: Operational conditions and economic assessment – A review. Desalination and Water Treatment, 271, 74-107. https://doi.org/10.5004/DWT.2022.28792

    Gautam, P., Kumar, S., Vishwakarma, S., & Gautam, A. (2022). Synergistic optimization of electrocoagulation process parameters using response surface methodology for treatment of hazardous waste landfill leachate. Chemosphere, 290. 133255. https://doi.org/10.1016/j.chemosphere.2021.133255

    Guo, Z., Zhang, Y., Jia, H., Guo, J., Meng, X., & Wang, J. (2022). Electrochemical methods for landfill leachate treatment: A review on electrocoagulation and electrooxidation. Science of The Total Environment, 806, 150529. https://doi.org/10.1016/J.SCITOTENV.2021.150529

    Hanif, M. H. M., Kamaruddin, M. A., Norashiddin, F. A., Niza, N. M., Shadi, A. M. H., Sabri, M. N. I. M., & Zawawi, M. H. (2022). Landfill leachate treatment technology via electrocoagulation: A review of operating parameters, intensification, and modelling. Desalination and Water Treatment, 260, 77-101. https://doi.org/10.5004/dwt.2022.28456

    Hussein, M., Yoneda, K., Mohd-Zaki, Z., Amir, A., & Othman, N. (2021). Heavy metals in leachate, impacted soils and natural soils of different landfills in Malaysia: An alarming threat. Chemosphere, 267, 128874. https://doi.org/10.1016/J.CHEMOSPHERE.2020.128874

    Kamaludin, M., Bohari, H., & Ponachi, N. S. (2021). Characteristics of raw leachate of Jeram sanitary landfill. Politeknik & Kolej Komuniti Journal of Life Long Learning, 5, 71-78.

    Lebron, Y. A. R., Moreira, V. R., Brasil, Y. L., Silva, A. F. R., Santos, L. V. de S., Lange, L. C., & Amaral, M. C. S. (2021). A survey on experiences in leachate treatment: Common practices, differences worldwide and future perspectives. Journal of Environmental Management, 288, 112475. https://doi.org/10.1016/J.JENVMAN.2021.112475

    López-Guzmán, M., Flores-Hidalgo, M. A., & Reynoso-Cuevas, L. (2021). Electrocoagulation process: An approach to continuous processes, reactors design, pharmaceuticals removal, and hybrid systems—A review. Processes, 9(10), 1831. https://doi.org/10.3390/pr9101831

    Nasrullah, M., Ansar, S., Krishnan, S., Singh, L., Peera, S. G., & Zularisam, A. W. (2022). Electrocoagulation treatment of raw palm oil mill effluent: Optimization process using high current application. Chemosphere, 299, 134387. https://doi.org/10.1016/J.CHEMOSPHERE.2022.134387

    Ogedey, A., & Oguz, E. (2024). Application of electrocoagulation process for the disposal of COD, NH3-N and turbidity from the intermediate sanitary landfill leachate. Environmental Science and Pollution Research, 31(7), 11243-11260. https://doi.org/10.1007/s11356-024-31937-7

    Rangga, J. U., Ismail, S. N. S., Rasdi, I., & Karuppiah, K. (2024). Estimation of leachate volume and treatment cost avoidance through waste segregation programme in Malaysia. Pertanika Journal of Science and Technology, 32(1), 339-364. https://doi.org/10.47836/pjst.32.1.19

    Rookesh, T., Samaei, M. R., Yousefinejad, S., Hashemi, H., Derakhshan, Z., Abbasi, F., Jalili, M., Giannakis, S., & Bilal, M. (2022). Investigating the electrocoagulation treatment of landfill leachate by iron/graphite electrodes: Process parameters and efficacy assessment. Water, 14(2), 205. https://doi.org/10.3390/w14020205

    Sadaf, S., Roy, H., Fariha, A., Rahman, T. U., Tasnim, N., Jahan, N., Sokan-Adeaga, A. A., Safwat, S. M., & Islam, M. S. (2024). Electrocoagulation-based wastewater treatment process and significance of anode materials for the overall improvement of the process: A critical review. Journal of Water Process Engineering, 62, 105409. https://doi.org/10.1016/J.JWPE.2024.105409

    Salim, A., El Bouari, A., Tahiri, M., & Tanane, O. (2024). Elimination of copper from wastewater arising from metal plating through electrocoagulation. Analytical and Bioanalytical Electrochemistry, 16(9), 817-829. https://doi.org/10.22034/abec.2024.716156

    Sediqi, S., Bazargan, A., & Mirbagheri, S. A. (2021). Consuming the least amount of energy and resources in landfill leachate electrocoagulation. Environmental Technology & Innovation, 22, 101454. https://doi.org/10.1016/J.ETI.2021.101454

    Shahedi, A., Darban, A. K., Taghipour, F., & Jamshidi-Zanjani, A. (2020). A review on industrial wastewater treatment via electrocoagulation processes. Current Opinion in Electrochemistry, 22, 154-169. https://doi.org/10.1016/J.COELEC.2020.05.009

    Sharma, L., Prabhakar, S., Tiwari, V., Dhar, A., & Halder, A. (2021). Optimization of EC parameters using Fe and Al electrodes for hydrogen production and wastewater treatment. Environmental Advances, 3, 100029. https://doi.org/10.1016/J.ENVADV.2020.100029

    Tahreen, A., Jami, M. S., & Ali, F. (2020). Role of electrocoagulation in wastewater treatment: A developmental review. Journal of Water Process Engineering, 37, 101440. https://doi.org/10.1016/j.jwpe.2020.101440

    Tay, K. W. W., Chin, S. F., Wasli, M. E., & Musa, Z. (2023). Response Surface Methodology: A versatile tool for the optimization of particle sizes of cellulose beads. Pertanika Journal of Science and Technology, 31(6), 2805-2822. https://doi.org/10.47836/pjst.31.6.10