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Sequestration of Pb(II) from Aqueous Environment by Palm Kernel Shell Activated Carbon: Isotherm and Kinetic Analyses

Ekemini Monday Isokise, Abdul Halim Abdullah and Tan Yen Ping

Pertanika Journal of Science & Technology, Volume 29, Issue 3, July 2021

DOI: https://doi.org/10.47836/pjst.29.3.17

Keywords: Activated carbon, adsorption, heavy metals, isotherm, palm kernel shell

Published on: 31 July 2021

In this work, activated carbons were produced by the thermochemical treatment of palm kernel shells with different activation time. The developed products (activated carbon samples) were described by their surface area, porosity, and applied for lead(II) ions separation from liquid phase. By prolonging the activation time beyond 2h, some of the micropores collapsed to form mesopores without causing a significant transformation in the surface area. The influences of solution pH, mass of biosorbents, concentration of Pb(II) ions, and temperature on the entrapment of lead(II) ions explored. Based on experimental outcome, the best-suited condition for the Pb(II) uptake was 0.13 g AC-4, 250 mg L-1 concentration, and pH 4. The Pb(II) entrapment process is thermodynamically exothermic and spontaneous. The adsorption data fit the Langmuir monolayer adsorption model, with 222 mg g-1 as maximum sorption capacity, and the Ho-second-order kinetics model suitably described the process rate.

  • Abdelwahab, O., Amin, N. K., & El-Ashtoukhy, E. S. Z. (2013). Removal of zinc ions from aqueous solution using a cation exchange resin. Chemical Engineering Research and Design, 91(1), 165-173. https://doi.org/10.1016/j.cherd.2012.07.005

  • Ademiluyi, F. T., & Nze, J. C. (2016). Multiple adsorption of heavy metal ions in aqueous solution using activated carbon from nigerian bamboo. International Journal of Research in Engineering and Technology, 5(1), 164-169. https://doi.org/10.15623/ijret.2016.0501033

  • Amarasinghe, B. M. W. P. K., & Williams, R. A. (2007). Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater. Chemical Engineering Journal, 132(1-3), 299-309. https://doi.org/10.1016/j.cej.2007.01.016.

  • Andas, J., Rahman, M. L. A., & Yahya, M. S. M. (2017). Preparation and characterization of activated carbon from palm kernel shell. In IOP Conference Series: Materials Science and Engineering (Vol. 226, No. 1, p. 012156). IOP Publishing. https://doi.org/10.1088/1757-899X/226/1/012156

  • Arshadi, M., Amiri, M. J., & Mousavi, S. (2014). Kinetic, equilibrium and thermodynamics investigation of Ni(II), Cd(II), Cu(II) and Co(II) adsorption on barley straw ash. Water Resource and Industry, 6, 1-17. https://doi.org/10.1016/j.wri.2014.06.001.

  • Baylan, N., & Meriçboyu, A. E. (2016). Adsorption of lead and copper on bentonite and grapeseed activated carbon in single- and binary-ion systems. Separation Science and Technology, 51(14), 2360-2368. 10.1080/01496395.2016.1212888.

  • EPA. (2017). National primary drinking water regulations. United States Environmental Protection Agency.

  • Gao, J. J., Qin, Y. B., Zhou, T., Cao, D. D., Xu, P., Hochstetter, D., & Wang, Y. F. (2013). Adsorption of methylene blue onto activated carbon produced from tea (Camellia sinensis L.) seed shells: Kinetics, equilibrium, and thermodynamics studies. Journal of Zhejiang University Science B, 14(7), 650-658. https://doi.org/10.1631/jzus.B12a0225.

  • Garcia, J. R., Sedron, U., Zaini, M. A. A., & Zakaria, Z. A. (2018). Preparation, characterization and dye removal study of carbon prepared from palm kernel shell. Environmental Science and Pollution Research, 25(6), 5076-5085. https://doi.org/10.1007/s11356-017-8975-8

  • Hannachi, Y., Hafidh, A., & Ayed, S. (2019). Effectiveness of novel xerogels adsorbents for cadmium uptake from aqueous solution in batch and column modes: Synthesis, characterization, equilibrium, and mechanism analysis. Chemical Engineering and Design, 143, 11-23. https://doi.org/10.1016/j.cherd.2019.01.006

  • Hidayu, A. R., & Muda, N. (2016). Preparation and characterization of impregnated activated carbon from palm kernel shell and coconut shell for CO2 capture. Procedia Engineering, 148, 106-113. https://doi.org/10.1016/j.proeng.2016.06.463

  • Imamoglu, M., & Oktay, T. (2008). Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228(1-3), 108-113. https://doi.org/10.1016/j.desal.2007.08.011.

  • Khadiran, T., Hussein, M. Z., Zainal, Z., & Rusli, R. (2014). Textural and chemical properties of activated carbon prepared from tropical peat soil by chemical activation method. BioResources, 10(1), 986-1007. https://doi.org/10.15376/biores.10.1.986-1007

  • Krika, F., Azzouz, N., & Ncibi, M. C. (2016). Adsorptive removal of cadmium from aqueous solution by cork biomass: Equilibrium, dynamics and thermodynamic studies. Arabian Journal of Chemistry, 9, S1077-S1083. https://doi.org/10.1016/j.arabjc.2011.12.013

  • Malik, D. S., Jain, C. K., & Yadav, A. K. (2016). Removal of heavy metals from emerging cellulosic low-cost adsorbents : A review. Applied Water Science 7, 2113-2136. https://doi.org/10.1007/s13201-016-0401-8.

  • Mopoung, S., Inkum, S., & Anuwetch, L. (2015). Effect of temperature on micropore of activated carbon from sticky rice straw by H3PO4 activation. Carbon-Science and Technology, 7(3), 24-29.

  • Mouni, L., Merabet, D., Bouzaza, A., & Belkhiri, L. (2011). Adsorption of Pb(II) from aqueous solutions using activated carbon developed from apricot stone. Desalination, 276(1-3), 148-53. https://doi.org/10.1016/j.desal.2011.03.038

  • Nunes, C. A., & Guerreiro, M. C. (2011). Estimation of surface area and pore volume of activated carbon by methylene blue and iodine numbers. Quimica Nova, 34(3), 472-476. https://doi.org/10.1590/S0100-40422011000300020 

  • Poudel, J., Ohm, T. I., Gu, J. H., Shin, M. C., & Oh, S. C. (2017). Comparative study of torrefaction of empty fruit bunches and palm kernel shell. Journal of Material Cycles and Waste Management, 19(2), 917-927. https://doi.org/10.1007/s10163-016-0492-1

  • Rashidi, N. A., & Yusuf, S. (2019). Production of palm kernel shell-based activated carbon by direct physical activation for carbon dioxide adsorption. Environmental Science and Pollution Research, 26(33), 33732-33746. https://doi.org/10.1007/s11356-018-1903-8

  • Razi, M. A. M., Al-Gheethi, A., Al-Qaini, M., & Yousef, A. (2018). Efficiency of activated carbon from kernel shell for treatment of grey water. Arab Journal of Basic and Applied Sciences, 25(3), 2018, 103-110.  https://doi.org/10.1080/25765299.2018.1514142

  • Rugayah, A. F., Astimar, A. A., & Norzita, N. (2014). Preparation and characterization of activated carbon from palm kernel shell by physical activation with steam. Journal of Oil Palm Research, 26(3), 251-264.

  • Sani, Y. M., Raji, A. O., Alaba, P. A., Aziz, A. R. A., & Daud, W. M. A. W. (2015). Palm frond and spikelet as environmentally benign alternative solid acid catalysts for biodiesel production. BioResources, 10(2), 3393-3408. https://doi.org/10.15376/biores.10.2.3393-3408

  • Shafie, S. M., Mahlia, T. M. I., Masjuki, H. H., & Ahmad-Yazid, A. (2012). A review on electricity generation based on biomass residue in Malaysia. Renewable and Sustainable Energy Reviews, 16(8), 5879-5889. https://doi.org/10.1016/j.rser.2012.06.031

  • Sayğılı, H., & Güzel, F. (2018). Novel and sustainable precursor for high-quality activated carbon preparation by conventional pyrolysis: Optimization of produce conditions and feasibility in adsorption studies. Advanced Powder Technology 29(3), 726-736. https://doi.org/10.1016/j.apt.2017.12.014.

  • Tang, C., Shu, Y., Zhang, R., Li, X., Song, J., Li, B., Zhang, Y., & Ou, D. (2017). Comparison of the removal and adsorption mechanisms of cadmium and lead from aqueous solution by activated carbons prepared from Typha Angustifolia and Salix Matsudana. RSC Advances, 7(26), 16092-16103. https://doi.org/10.1039/C6RA28035H

  • Wang, L., & Jian, L. (2013). Removal of methylene blue from aqueous solution by adsorption onto crofton weed stalk. BioResources 8(2), 2521-2536.

  • Wang, Z., Shirley, M. D., Meikle, S. T., Whitby, R. L. D., & Mikhalovsky, S. V. (2009). The surface acidity of acid oxidised multi-walled carbon nanotubes and the influence of in-situ generated fulvic acids on their stability in aqueous dispersions. Carbon 47(1), 73-79. https://doi.org/10.1016/j.carbon.2008.09.038

  • Xu, M., Li, D., Yan, Y., Guo, T., Pang, H., & Xue, H. (2017). Porous high specific surface area-activated carbon with co-doping N, S and P for high-performance supercapacitors. RSC Advances 7(69), 43780-43788. https://doi.org/10.1039/C7RA07945A

  • Yeung, P. T., Chung, P. Y., Tsang, H. C., Tang, J. C. O., Cheng, G. Y. M., Gambari, R., Chui, C. H., & Lam, K. H. (2014). Preparation and characterization of bio-safe activated charcoal derived from coffee waste residue and its application for removal of lead and copper ions. RSC Advances, 4(73), 38839-38847. https://doi.org/10.1039/C4RA05082G

  • Zaini, M. A. A., Okayama, R., & Machida, M. (2009). Adsorption of aqueous metal ions on cattle-manure-compost based activated carbons. Journal of Hazardous Materials, 170(2-3), 1119-1124. https://doi.org/10.1016/j.jhazmat.2009.05.090

  • Zuo, X. (2014). Preparation and evaluation of novel thiourea / chitosan composite beads for copper(II) removal in aqueous solutions. Industrial and Engineering Chemistry Research, 53(3), 1249-1255. https://doi.org/10.1021/ie4036059

ISSN 0128-7680

e-ISSN 2231-8526

Article ID

JST-2374-2020

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